1369356-06-8

Basic information

• Product Name: 1-benzyl-3-[(2Z)-2-tert-butyl-5,5-dimethyl-4-oxohex-2-en-1-yl]-1H-benzimidazol-3-ium bromide
• CAS NO: 1369356-06-8
• Molecular Weight: 469.465
• Mol File: 1369356-06-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-benzyl-3-[(2Z)-2-tert-butyl-5,5-dimethyl-4-oxohex-2-en-1-yl]-1H-benzimidazol-3-ium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzyl-3-[(2Z)-2-tert-butyl-5,5-dimethyl-4-oxohex-2-en-1-yl]-1H-benzimidazol-3-ium bromide(1369356-06-8)
• EPA Substance Registry System: 1-benzyl-3-[(2Z)-2-tert-butyl-5,5-dimethyl-4-oxohex-2-en-1-yl]-1H-benzimidazol-3-ium bromide(1369356-06-8)

Safety Data

• Hazardous Substances Data: 1369356-06-8(Hazardous Substances Data)

Upstream product

• 4981-92-4 1-benzylbenzimidazole 
• 35606-00-9 (4Z)-5-(bromo-methyl)-2,2,6,6-tetramethylhept-4-en-3-one 

Downstream Products

• 1369356-16-0 5-benzyl-2,4-di(tert-butyl)-5H-pyrido[1,2-a]benzimidazol-10-ium bromide 

Relevant articles and documents

Synthesis of azolo[a]pyridines from 5-(bromomethyl)hept-4-en-3-one and 5-bromopent-3-en-2-one derivatives

Alkyl derivatives of 1H-imidazo[1,2-a]pyridin-4-ium, 5H-pyrido[1,2-a] benzimidazol-10-ium, 1H-[1,2,4]-triazolo[4,3-a]pyridin-4-ium, and 3-methylthiazolo[3,2-a]pyridin-4-ium bromides were obtained in two stages from (4Z)-5-(bromomethyl)-2,2,6,6-tetramethylhept-4-en-3-one, 5-bromo-4-methylpent-3- en-2-one, or (3E)-5-bromopent-3-en-2-one by alkylation of 1-alkyl-1H-imidazoles, 1-alkyl-1H-benz-imidazoles, 1-methyl-1H-1,2,4-triazole, and 4-methylthiazole and subsequent cyclization of the quaternary azolium salts in the presence of bases.