136945-23-8

Upstream product

• 107-69-7 Voluntal 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 2873-29-2 D-glucal triacetate 

Downstream Products

• 807355-16-4 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-[tert-butyl-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyloxy)-phenyl-silanyloxy]-5-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester 
• 1372616-72-2 1,6-di-O-benzyl-4-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloro-ethoxycarbonylamino)-α-D-glucopyranosyl]-3-O-(2,2,2-trichloro-ethoxycarbonyl)-2-deoxy-2-(2,2,2-trichloro-ethoxy-carbonylamino)-α-D-glucopyranoside 
• 1372616-73-3 1,6-Di-O-benzyl-4-O-[3,4,6-tri-O-acetyl-2-acetamido-α-D-glucopyranosyl]-2-acetamido-α-D-glucopyranoside 
• 220645-20-5 p-methylphenyl 3,4,6-tri-O-acetyl-2-deoxy-1-thio-2-(2,2,2-trichloroethyloxycarbonylamino)-β-D-glucopyranoside 
• 160067-63-0 N^α-(9-flourenylmethoxycarbonyl)-3-O-(2-acetamido-2-deoxy-3,4,6-tri-O-acetyl-Β-D-glucopyranosyl)-L-serine 
• 1380522-52-0 C₄₉H₇₁N₂O₂₅PS 
• 1380522-42-8 C₆₀H₉₅N₄O₂₄P 
• 1380522-17-7 N-acetyl-4-O-(3,4,6-tri-O-acetyl-2-acetylamino-2-deoxy-β-D-glucopyranosyl)-α-D-muramic acid, 6-acetate, 1-(benzyl hexadecyl phosphate) 
• 1380522-11-1 C₅₈H₈₇N₂O₂₂PS 
• 133940-44-0 benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside 
• 136945-17-0 O-(2-Acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-1-O-acetyl-3,4,6-tri-O-benzyl-D-mannopyranose 

Relevant academic research and scientific papers

Convenient stereocontrolled amidoglycosylation of alcohols with acetylated glycals and trichloroethoxysulfonamide

A regio- and stereo-controlled, rhodium(II)-catalyzed amidoglycosylation of alcohols has been developed using O-acetylated glycals, trichloroethoxysulfonamide, and iodosobenzene. This one-pot amidoglycosylation was applied to a variety of primary and secondary alcohols to afford the β-O-glycosides with acceptable yields up to 84%. The reaction would proceed via stereoselective intermolecular aziridination of the glycal from the α-face followed by SN2 reaction with alcohol at C-1 from the β-face to give 1,2:2,3-di-trans-substituted isomer only.