1369591-86-5Relevant academic research and scientific papers
A Hydrosilylation Approach to Silicon-Bridged Functional Dipyrromethanes: Introducing Silicon to A New Arena
Garg, Bhaskar,Bisht, Tanuja,Ling, Yong-Chien
, p. 66 - 71 (2020)
Two silylene-spaced ((E)-vinylsilyl)anthracene-dipyrromethane dyads have been designed and synthesized by RhCl(PPh3)3-catalyzed hydrosilylation reactions of 5-methyl-5′-(ethynylaryl)dipyrromethanes with (9-Anthryl)-dimethylsilane. Th
Polyatomic anion assistance in the assembly of [2]pseudorotaxanes
Valderrey, Virginia,Escudero-Adan, Eduardo C.,Ballester, Pablo
supporting information; experimental part, p. 10733 - 10736 (2012/08/27)
We describe the use of polyatomic anions for the quantitative assembly of ion-paired complexes displaying pseudorotaxane topology. Our approach exploits the unique ion-pair recognition properties exhibited by noncovalent neutral receptors assembled through hydrogen-bonding interactions between a bis-calix[4]pyrrole macrocycle and linear bis-amidepyridyl-N-oxides. The complexation of bidentate polyatomic anions that are complementary in size and shape to the receptor's cavity, in which six NH hydrogen-bond donors converge, induces the exclusive formation of four particle-threaded assemblies.
