136962-67-9

Basic information

• Product Name: (R)-1-phenylethyl-1,3,2-benzodioxaborole
• Synonyms: (R)-1-phenylethyl-1,3,2-benzodioxaborole
• CAS NO: 136962-67-9
• Molecular Weight: 224.067
• Mol File: 136962-67-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-1-phenylethyl-1,3,2-benzodioxaborole(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-phenylethyl-1,3,2-benzodioxaborole(136962-67-9)
• EPA Substance Registry System: (R)-1-phenylethyl-1,3,2-benzodioxaborole(136962-67-9)

Safety Data

• Hazardous Substances Data: 136962-67-9(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 274-07-7 benzo[1,3,2]dioxaborole 

Downstream Products

• 59850-51-0 (2R,3R)-2-acetylamino-3-methyl-3-phenylalanine hydrochloride 
• 53331-55-8 (2S,3S)-β-methylphenylalanine hydrochloride 
• 59850-51-0 threo-(+)-(2S,3R)-L-β-Methylphenylalanine hydrochloride 
• 505094-34-8 (R)-9-(1-phenylethyl)-9-borabicyclo[3.3.1]nonane 
• 59850-51-0 (2R,3S)-2-amino-3-phenyl-butyric acid hydrochloride 
• 505094-50-8 1,1-dimethylethyl N-(diphenylmethylene)-(βS)-methyl-D-phenylalaninate 
• 505094-48-4 1,1-dimethylethyl N-(diphenylmethylene)-(βR)-methyl-D-phenylalaninate 
• 505094-49-5 1,1-dimethylethyl N-(diphenylmethylene)-(βS)-methyl-L-phenylalaninate 
• 505094-47-3 1,1-dimethylethyl N-(diphenylmethylene)-(βR)-methyl-L-phenylalaninate 
• 1517-69-7 (R)-1-phenylethanol 

Relevant articles and documents

Rh(I)-catalyzed asymmetric hydrosilylation and hydroboration/oxidation reactions using berens ligand

The Berens ligand 2 was used in a number of Rh(I)-catalyzed asymmetric hydrosilylations of acetophenones under standard conditions, affording the corresponding 1-arylalcohols in ees up to 65%. Some novel Rh catalysts were generated in situ from the neutral precatalyst [Rh(μ-Cl)(COD)]2 and screened in the catalytic asymmetric hydroboration/oxidation of styrenes, gave enantioselectivities of up to 62%. Copyright Taylor & Francis Group, LLC.