136969-83-0

Basic information

• Product Name: 1H-1,3-Benzodiazepine-4-carboxylic acid, 2-phenyl-, ethyl ester
• CAS NO: 136969-83-0
• Molecular Formula: C18H16N2O2
• Molecular Weight: 292.337
• Mol File: 136969-83-0.mol

Chemical Properties

• CAS DataBase Reference: 1H-1,3-Benzodiazepine-4-carboxylic acid, 2-phenyl-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-1,3-Benzodiazepine-4-carboxylic acid, 2-phenyl-, ethyl ester(136969-83-0)
• EPA Substance Registry System: 1H-1,3-Benzodiazepine-4-carboxylic acid, 2-phenyl-, ethyl ester(136969-83-0)

Safety Data

• Hazardous Substances Data: 136969-83-0(Hazardous Substances Data)

Upstream product

• 139547-74-3 C₃₆H₃₁N₂O₃P 
• 136969-78-3 (Z)-2-Azido-3-(2-azido-phenyl)-acrylic acid ethyl ester 
• 16714-25-3 2-azidobenzaldehyde 
• 98-88-4 benzoyl chloride 
• 136969-79-4 C₄₇H₄₀N₂O₂P₂ 
• 136969-79-4 C₄₇H₄₀N₂O₂P₂ 

Downstream Products

• 136969-84-1 2-Phenyl-2,3-dihydro-1H-benzo[d][1,3]diazepine-4-carboxylic acid ethyl ester 

Relevant articles and documents

A New Route to 1,3-Benzoxazepines and 1,3-Benzodiazepines via Intramolecular Aza-Wittig Reaction

The reaction of triphenylphosphine with the o-acyloxy-5 and o-acylamino-azidocinnamates 9, prepared from salicylaldehyde and o-aminobenzaldehyde, results in ring closure to give the 1,3-benzoxazepines 7 and 1,3-benzodiazepines 12, via the intramolecular a

Preparation, Reactivity and Synthetic Applications of Bis(iminophosphoranes): New Entries to Fused 1,3,5-Benzotriazepines, 1,3-Benzodiazepines and Indole Derivatives

An aza-Wittig-type reaction of bis(iminophosphorane) 2 with two moles of alkyl or aryl iso(thio)cyanates leads to indazolotriazolobenzotriazepines 7.The bis(iminiphosphorane) 4 reacts with aromatic iso(thio)cyanates to give

Iminophosphorane-mediated synthesis of functionalized indoles and 1,3-benzodiazepines

Aza Wittig-type reaction of bis(iminophosphorane) 2 with aromatic isocyanates leads to either indoles 5 or pyrimido[4,5-b]indoles 6, whereas with aliphatic isocyanates and acyl chlorides afforded pyrrolo[2,3-b]indoles 7 and 1,3-benzodiazepines 10 respectively.