1369761-90-9

Basic information

• Product Name: [1-bromo-1-(1,1,2,2-tetrafluoroethoxy)methyl]phenylketone
• Synonyms: [1-bromo-1-(1,1,2,2-tetrafluoroethoxy)methyl]phenylketone
• CAS NO: 1369761-90-9
• Molecular Weight: 315.062
• Mol File: 1369761-90-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1-bromo-1-(1,1,2,2-tetrafluoroethoxy)methyl]phenylketone(CAS DataBase Reference)
• NIST Chemistry Reference: [1-bromo-1-(1,1,2,2-tetrafluoroethoxy)methyl]phenylketone(1369761-90-9)
• EPA Substance Registry System: [1-bromo-1-(1,1,2,2-tetrafluoroethoxy)methyl]phenylketone(1369761-90-9)

Safety Data

• Hazardous Substances Data: 1369761-90-9(Hazardous Substances Data)

Upstream product

• 28203-05-6 dimethoxy-2,2 phenyl-2 ethanol-1 
• 1369761-88-5 phenyl[(1,1,2,2-tetrafluoroethoxy)methyl]ketone 
• 1369761-86-3 1-phenyl-1,1-dimethoxy-2-(1,1,2,2-tetrafluoroethoxy)ethane 

Downstream Products

• 1369762-01-5 3-phenyl-2-(1,1,2,2-tetrafluoroethoxy)-2,3-dihydrobenzo[4,5]imidazo[2,1-b]thiazol-3-ol 
• 1369762-02-6 3-chloro-3-phenyl-2-(1,1,2,2-tetrafluoroethoxy)-2,3-dihydro-benzo[4,5]imidazo[2,1-b]thiazole 
• 1369762-03-7 3-phenyl-2-(1,1,2,2-tetrafluoroethoxy)benzo[4,5]imidazo[2,1-b]thiazole 
• 1369761-94-3 [5-(1,1,2,2-tetrafluoroethoxy)-4-phenylthiazol-2-yl]amine 
• 1369762-04-8 2,4-diphenyl-5-(1,1,2,2-tetrafluoroethoxy)thiazole 
• 1369762-00-4 [3-methyl-4-phenyl-5-(1,1,2,2-tetrafluoroethoxy)-3H-thiazol-2-ylidene]phenylamine 
• 1369761-99-8 phenyl-[4-phenyl-5-(1,1,2,2-tetrafluoroethoxy)thiazol-2-yl]amine 

Relevant articles and documents

Efficient synthesis of 5′-fluoroalkoxythiazoles via α-bromo-α-fluoroalkoxyacetophenones Hantzsch type cyclization with thioureas or thioamides

Novel α-fluoroalkoxyacetophenones were synthesized by addition of the readily available 2,2-dimethoxy-2-phenylethanol to fluoroolefins. α-Bromination yielded α-bromo-α-fluoroalkoxyacetophenones, which on treatment with thioureas or thioamides gave thiazoles with fluoroalkoxy groups at the 5′-position by the Hantzsch-type cyclization. This provides a versatile methodology for the construction of heterocycles from aliphatic fluoroalkoxy containing building blocks.