136994-75-7

Basic information

• Product Name: (E)-3-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(diethoxy-phosphoryl)-acrylic acid ethyl ester
• CAS NO: 136994-75-7
• Molecular Weight: 484.483
• Mol File: 136994-75-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-3-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(diethoxy-phosphoryl)-acrylic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(diethoxy-phosphoryl)-acrylic acid ethyl ester(136994-75-7)
• EPA Substance Registry System: (E)-3-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(diethoxy-phosphoryl)-acrylic acid ethyl ester(136994-75-7)

Safety Data

• Hazardous Substances Data: 136994-75-7(Hazardous Substances Data)

Upstream product

• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 102919-04-0 benzyl 2,3-O-isopropylidene-α-D-lyxo-pentodialdo-1,4-furanoside 

Downstream Products

• 136994-78-0 ethyl (3R,4S,5S)-3,4-isopropylidenedioxy-5-hydroxy-cyclohex-1-ene-1-carboxylate 
• 90927-40-5 (3R,4S,5S)-5-hydroxy-3,4-(isopropylidenedioxy)cyclohex-1-enecarboxylic acid 
• 158341-64-1 (3R,4S,5S)-3,4,5-trihydroxycyclohex-1-enecarboxylic acid 

Relevant articles and documents

Synthesis of shikimic acid and its phosphonate analogue via knoevenagel condensation

The Knoevenagel condensation and intramolecular olefination have been successfully exploited in a novel synthesis of shikimic acid 1 and its phosphonate analogue 2 from D-lyxose 5-aldehyde 7.