1370254-71-9Relevant academic research and scientific papers
A facile one-pot synthesis of α-halo,α-allylic aldehydes from α,α-dihalo ketones utilizing allylic zinc bromide
Wang, Xiaolei,Zhang, Songlin
, p. 96 - 102 (2012)
An efficient synthesis of various α-halo,α-allylic aldehydes from α,α-dihalo ketones using both cyclic (3-bromocyclohex-1-ene zinc bromide and (Z)-3-bromocyclobut-1-ene zinc bromide) and acyclic (allylzinc bromide and cinnamylzinc bromide) type of allylic organozinc bromide with DMF as base is described. A possible reaction mechanism is also proposed. Copyright
