1370548-95-0Relevant academic research and scientific papers
Heteroatom-directed Wacker oxidations. A protection-free synthesis of (-)-heliophenanthrone
Mukherjee, Parag,Sarkar, Tarun K.
, p. 3060 - 3065 (2012/05/07)
The first enantioselective six-step synthesis of (-)-heliophenanthrone has been achieved without any protection-deprotection protocol at an overall yield of 28%. Key features of this synthesis comprise a heteroatom-directed Wacker oxidation of an internal cyclic olefin in addition to asymmetric Brown allylation and ring closing metathesis (RCM). The Royal Society of Chemistry 2012.
