1370590-19-4

Basic information

• Product Name: ethyl 5-(4-(3-ethoxy-3-oxoprop-1-en-1-yl)phenyl)pent-2-enoate
• Synonyms: ethyl 5-(4-(3-ethoxy-3-oxoprop-1-en-1-yl)phenyl)pent-2-enoate
• CAS NO: 1370590-19-4
• Molecular Weight: 302.37
• Mol File: 1370590-19-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 5-(4-(3-ethoxy-3-oxoprop-1-en-1-yl)phenyl)pent-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 5-(4-(3-ethoxy-3-oxoprop-1-en-1-yl)phenyl)pent-2-enoate(1370590-19-4)
• EPA Substance Registry System: ethyl 5-(4-(3-ethoxy-3-oxoprop-1-en-1-yl)phenyl)pent-2-enoate(1370590-19-4)

Safety Data

• Hazardous Substances Data: 1370590-19-4(Hazardous Substances Data)

Upstream product

• 287208-66-6 1-iodo-4-(iodomethyl)benzene 
• 105-36-2 ethyl bromoacetate 
• 107-18-6 allyl alcohol 

Relevant articles and documents

A novel consecutive three-component Heck-isomerization-Wittig sequence by way of in situ generated aldehydes

A novel consecutive three-component four step synthesis of 5-(hetero)arylpent-2-enoates has been disclosed. Various (hetero)aryl iodides can be coupled with allyl alcohol under Heck conditions to give 3-(hetero)arylpropionaldehyde intermediates, which were transformed without isolation with in situ generated stabilized phosphorus ylides to furnish 5-(hetero)arylpent-2-enoates in moderate to excellent yield. This one-pot procedure circumvents the isolation of sensitive aldehydes and phosphorus ylides as intermediates and finally gives the product isomers with good to excellent E/Z and β/α selectivity. ARKAT-USA, Inc.