137100-95-9

Upstream product

• 137100-93-7 methyl 2-S-benzoyl-4-O-benzoyl-6-bromo-2,6-dideoxy-3-O-tetrahydropyranyl-α-L-altropyranoside 
• 137100-92-6 Benzoic acid (2R,3R,4S,5R,6R)-5-benzoylsulfanyl-2-bromomethyl-4-hydroxy-6-methoxy-tetrahydro-pyran-3-yl ester 
• 110-87-2 3,4-dihydro-2H-pyran 
• 100-39-0 benzyl bromide 
• 137100-94-8 methyl 2,6-anhydro-3-O-tetrahydropyranyl-2-thio-α-L-altropyranoside 

Downstream Products

• 137100-97-1 methyl 2,6-anhydro-4-O-benzyl-2-thio-β-L-altropyranoside 
• 137100-96-0 methyl 2,6-anhydro-4-O-benzyl-2-thio-α-L-altropyranoside 
• 137101-00-9 methyl 2,6-anhydro-4-O-benzyl-3-C-methyl-2-thio-α-L-altropyranoside 
• 137101-01-0 (1R,3R,4R,7S,8R)-7-Benzyloxy-3-methoxy-8-methyl-2-oxa-5-thia-bicyclo[2.2.2]octan-8-ol 
• 137101-04-3 methyl 2,6-anhydro-4-O-benzyl-3-C-methyl-3-O-methyl-2-thio-α-L-altropyranoside 
• 137100-98-2 methyl 2,6-anhydro-4-O-benzyl-2-thio-α-L-arabino-hexopyranosid-3-ulose 
• 139573-81-2 methyl 2,6-anhydro-4-O-benzyl-3-O-methyl-2-thio-α-L-altropyranoside 
• 137100-99-3 methyl 2,6-anhydro-4-O-benzyl-2-thio-β-L-arabino-hexopyranosid-3-ulose 
• 137101-05-4 methyl 2,6-anhydro-4-O-benzyl-3-C-methyl-3-O-methyl-2-thio-β-L-mannopyranoside 
• 137101-02-1 methyl 2,6-anhydro-4-O-benzyl-3-C-methyl-2-thio-β-L-mannopyranoside 
• 137101-03-2 (1R,3S,4R,7S,8S)-7-Benzyloxy-3-methoxy-8-methyl-2-oxa-5-thia-bicyclo[2.2.2]octan-8-ol 

Relevant academic research and scientific papers

De novo highly stereocontrolled synthesis of 2,6-dideoxy sugars by use of 2,6-anhydro-2-thio sugars

Representative 2,6-dideoxy sugars, L-cladinose (1), L-(mycarose (2), L-oleandrose (3), L-olivose (4), and all of their C-3 epimers, 2,6-dideoxy-3-C-methyl-3-O-methyl-L-arabino-hexopyranose (26), 2,6-dideoxy-3-C-methyl-L-arabino-hexopyranose (L-olivomycose

De Novo highly stereocontrolled synthesis of 2,6-dideoxy-C-3-branched carbohydrates by use of 2,6-anhydro-2-thio sugar:L-cladinose and its C-3 epimer

L-Cladinose (1) and its C-3 epimer 2 were synthesized through a highly stereo selective addition of methyl anion to the C-3 carbonyl groups of α-anomer 9 and β-anomer 10 having 2,6-anhydro-2-thio structures, respectively, which were prepared from the comm