137114-69-3Relevant academic research and scientific papers
Pd-catalyzed aerobic direct olefination of polyfluoroarenes
He, Chun-Yang,Qing, Feng-Ling,Zhang, Xingang
supporting information, p. 2962 - 2964 (2014/05/06)
The first example of Pd-catalyzed aerobic direct olefination of polyfluoroarenes has been developed. The reaction makes use of molecular O 2 as terminal oxidant, and provides a cost-efficient and environmentally benign access to polyfluoroarene-alkene structures that are of interest in life and material sciences.
Rh(I)-Catalyzed olefin hydroarylation with electron-deficient perfluoroarenes
Sun, Zhong-Ming,Zhang, Jing,Manan, Rajith S.,Zhao, Pinjing
supporting information; experimental part, p. 6935 - 6937 (2010/08/06)
Assisted by a partially aqueous media, a catalyst system of [Rh(cod)(OH)]2 and DPPBenzene ligand effectively promotes direct conjugate additions by perfluoroarenes. This formal C-H alkylation process represents a rare example of olefin hydroarylation with electron-deficient arenes. The catalyst system can be modified to selectively form the corresponding olefination products under anhydrous conditions.
Development of a decarboxylative palladation reaction and its use in a Heck-type olefination of arene carboxylates
Myers, Andrew G.,Tanaka, Daisuke,Mannion, Michael R.
, p. 11250 - 11251 (2007/10/03)
The development of a palladium-catalyzed decarboxylative coupling reaction of arene carboxylates with olefinic substrates is described. The optimized procedure for decarboxylative palladation employs Pd(O2CCF3)2 as catalys
A novel one-pot synthesis of fluorinated α,β-unsaturated esters
Shen,Xiang
, p. 1403 - 1408 (2007/10/02)
The reaction of pentafluorophenylmethylenetriphenylarsorane or p-chloro-tetrafluorophenylmethylenetriphenylarsorane, generated in situ from methylenetriphenylarsorane and hexafluorobenzene or chloropentafluorobenzene, with bromoacetates giving excellent y
