137151-62-3

Basic information

• Product Name: Benzene, [3-[(1-methylethenyl)oxy]-1-propenyl]-, (E)-
• CAS NO: 137151-62-3
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 137151-62-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [3-[(1-methylethenyl)oxy]-1-propenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [3-[(1-methylethenyl)oxy]-1-propenyl]-, (E)-(137151-62-3)
• EPA Substance Registry System: Benzene, [3-[(1-methylethenyl)oxy]-1-propenyl]-, (E)-(137151-62-3)

Safety Data

• Hazardous Substances Data: 137151-62-3(Hazardous Substances Data)

Upstream product

• 116-11-0 2-Methoxypropene 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Downstream Products

• 50552-30-2 4-phenyl-5-hexen-2-one 

Relevant articles and documents

Highly regioselective [3,3] rearrangement of aliphatic allyl vinyl ethers catalyzed by a metalloporphyrin complex, Cr(TPP)Cl

The Claisen rearrangement of simple aliphatic allyl vinyl ethers catalyzed by a metalloporphyrin, Cr(TPP)Cl, is described. The porphyrin-based Lewis acid catalyst can effectively accelerate the rearrangement via a concerted [3,3] pathway with a minimal degree of bond ionization of the substrates, providing the corresponding Claisen products in moderate to high yields and almost perfect regioselectivity at low catalyst loading.