137160-76-0

Basic information

• Product Name: ACETOXIME BENZOATE
• Synonyms: ACETOXIME BENZOATE;ACETONE O-(BENZYLOXYCARBONYL)OXIME;BENZOIC ACID ACETOXIME ESTER;O-BENZOYLACETOXIME
• CAS NO: 137160-76-0
• Molecular Formula: C₁₁H₁₃NO₃
• Molecular Weight: 207.23
• Product Categories: Nitrogen Compounds;Organic Building Blocks;Oximes
• Mol File: 137160-76-0.mol
• Article Data: 3

Chemical Properties

• Melting Point: 46-48 °C(lit.)
• Boiling Point: 290.3°C at 760 mmHg
• Flash Point: 122.5°C
• Appearance: /
• Density: 1.06g/cm³
• Vapor Pressure: 0.00209mmHg at 25°C
• Refractive Index: 1.498
• CAS DataBase Reference: ACETOXIME BENZOATE(CAS DataBase Reference)
• NIST Chemistry Reference: ACETOXIME BENZOATE(137160-76-0)
• EPA Substance Registry System: ACETOXIME BENZOATE(137160-76-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 137160-76-0(Hazardous Substances Data)

Usage

Uses

Acetoxime Benzoate is a useful research intermediate for organic synthesis. Oxime derivative.

InChI:InChI=1/C11H13NO3/c1-9(2)12-15-11(13)14-8-10-6-4-3-5-7-10/h3-7H,8H2,1-2H3

Upstream product

• 501-53-1 benzyl chloroformate 
• 127-06-0 acetone oxime 

Downstream Products

• 137160-74-8 (+/-)-2-benzyloxycarbonylaminobutan-1-ol 
• 87905-98-4 5-<(benzyloxycarbonyl)amino>pentanol 
• 17996-12-2 N-benzyloxycarbonyl-6-amino-1-hexanol 
• 145799-48-0 (R)-(+)-benzyl 2-(benzyloxycarbonylamino)butyl carbonate 
• 145799-48-0 (S)-(-)-benzyl 2-(benzyloxycarbonylamino)butyl carbonate 
• 139705-34-3 benzyl (2R,3S,5R)-5-(2,4-dioxo-3,4-dihydropyrimidin-1 (2H)-yl)-2-(hydroxymethyl)tetrahydrofuran-3-yl carbonate 
• 145799-49-1 (R)-(+)-benzyl 2-(benzyloxycarbonylamino)pentyl carbonate 
• 145799-50-4 (R)-(+)-benzyl 2-(benzyloxycarbonylamino)hexyl carbonate 
• 145799-50-4 (S)-(-)-benzyl 2-(benzyloxycarbonylamino)hexyl carbonate 
• 139705-33-2 3'-O-(benzyloxycarbonyl)thymidine 
• 146457-41-2 C₁₃H₁₇N₃O₈ 
• 34637-22-4 3-[(N-benzyloxycarbonyl)amino]propanol 

Relevant articles and documents

Lipase-mediated Alkoxycarbonylation of Nucleosides with Oxime Carbonates.

5'-O-Carbonates of ribonucleosides and 2'-deoxyribonucleosides could be obtained by enzymatic alkoxycarbonylation with SP 435 lipase (from Candida antarctica) and oxime carbonates, which are easily prepared from chloroformates.Ribonucleosides gave as resu

Oxime esters as acylating agents in the aminolysis reaction. A simple and chemoselective method for the preparation of amides from amino alcohols

Oxime esters, such as acetone O-alkanoyl-, O-alkenoyl- or O-benzyloxycarbonyloximes, react with amines under extremely mild conditions to give the corresponding amides in very good yield. When amino alcohols are used a total chemoselectivity is observed.