137203-44-2Relevant academic research and scientific papers
Reactions of electron-rich arylpalladium complexes with olefins. Origin of the chelate effect in vinylation catalysis
Portnoy,Ben-David,Rousso,Milstein
, p. 3465 - 3479 (2008/10/08)
Reaction of (dippp)Pd(Ph)Cl (1) with norbornene or styrene yields (dippp)PdCl2 (8) and (dippp)Pd(η2-olefin). Kinetic follow-up reveals fast formation of (dippp)Pd(phenylnorbornyl)-Cl (10), followed by its slow decomposition, with ks
