13721-91-0Relevant academic research and scientific papers
Les triorganosilylpotasium: nouvelle voie d'acces et quelques aspects de leur reactivite
Corriu, R. J. P .,Guerin, C.,Kolani, B.
, p. 973 - 979 (2007/10/02)
We report here a new procedure for the convenient and easy preparation of silylanions and especially of Me3Si-.These undergo coupling reaction with halides and α-enone in good yields.Reactions with 5-bromo-1 hexene, benzophenone and carbon dioxide provide evidence for the ability of the silylpotassium to act as monoelectron transfer reagents.The course of these reactions varies substantially with the nature of the solvent.
