137219-83-1Relevant articles and documents
Transition Metal-Free Synthesis of α-Aminophosphine Oxides through C(sp3)?P Coupling of 2-Azaallyls
Wang, Jing,Deng, Guogang,Liu, Chunxiang,Chen, Zhuo,Yu, Kaili,Chen, Wen,Zhang, Hongbin,Yang, Xiaodong
, p. 2268 - 2273 (2020/03/04)
Radical reactions have been widely applied in C?P bond-forming strategies. Most of these strategies require initiators, transition metal catalysts, or organometallic reagents. Herein, a transition metal-free C(sp3)?P bond formation to prepare α
Phosphazene-based host materials for the use in blue phosphorescent organic light-emitting diodes
Schroegel, Pamela,Hoping, Matthias,Kowalsky, Wolfgang,Hunze, Arvid,Wagenblast, Gerhard,Lennartz, Christian,Strohriegl, Peter
experimental part, p. 4947 - 4953 (2012/04/04)
We present a series of low-molecular-weight materials based on cyclic phosphazenes for the use as host materials in blue phosphorescent organic light-emitting diodes. Substituted phenyl rings are attached to the central phosphazene ring either via phosphorus-oxygen bonds to yield phenoxy-substituted derivatives or via direct phosphorus-carbon bonds to yield phenyl-substituted derivatives. The phenoxy substituted cyclic phosphazenes were prepared by nucleophilic substitution of the six chlorine atoms in hexachlorocyclotriphosphazene with phenoxy groups, whereas the phenyl substituted cyclic phosphazenes were formed in a cyclocondensation reaction of three equivalents of substituted phosphinic amides. The phenyl substitution leads to materials with superior thermal properties compared to the phenoxy substitution. Because of the nonconjugated linkage to the phosphazene core, the host materials have very high triplet energies of more than 3 eV. In an OLED device using one compound as host for the saturated blue phosphorescent emitter Ir(dbfmi), a peak power efficiency of 7.6 lm W-1 and a peak luminance of 5000 cd m-2 were achieved.
Kinetic resolution of hydroperoxides with enantiopure phosphines: Preparation of enantioenriched tertiary hydroperoxides
Driver, Tom G.,Harris, Jason R.,Woerpel
, p. 3836 - 3837 (2008/02/13)
An efficient reductive kinetic resolution strategy capable of accessing optically active tertiary hydroperoxides is reported. Readily accessible tertiary hydroperoxides are resolved with commercially available (R)- or (S)-xylyl-PHANEPHOS with selectivity factors as large as 37. The resulting bis(phosphine oxide) can be recycled in high yields. The isolated mono(phosphine oxide) intermediate resolved hydroperoxides with the same selectivity as the parent bisphosphine. Copyright
Stereospecific deoxygenation of phosphine oxides with retention of configuration using triphenylphosphine or triethyl phosphite as an oxygen acceptor
Wu, Hai-Chen,Yu, Jin-Quan,Spencer, Jonathan B.
, p. 4675 - 4678 (2007/10/03)
(Chemical Equation Presented) A new protocol for deoxygenation of various phosphine oxides with retention of configuration is described. The advantage of the new method includes milder conditions and considerably shortened reaction times. Mechanistic studies about the oxygen transfer between the starting phosphine oxide and the sacrificial triphenylphosphine are also presented.
Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of α- and β-Functionalized Ketones
Mashima, Kazushi,Kusano, Koh-hei,Sato, Naomasa,Matsumura, Yoh-ichi,Nozaki, Kyoko,et al.
, p. 3064 - 3076 (2007/10/02)
Cationic ruthenium-BINAP complexes 5, 7, and 10 of the formula Y, where X = Cl, Br, I; Y = Cl, Br, I, BF4, B(C6H5)4; arene = benzene, p-cymene, ethyl benzoate, and their enantiomers have been prepared by the reaction of arene-ruthenium halide complexes 4, 6, and 9 with (S)-BINAP or (R)-BINAP.Structures of the complexes were established by spectroscopy, conductivity, and a single-crystal X-ray analysis (5d: orthorhombic, P21212; a=20.141(2) Angstroem, b=18.504(1) Angstroem, c=12.241(1) Angstroem, V=4562.0(7) Angstroem3, Z=4, R=0.078 for unique 4177 reflections).BINAP derivatives with various substituents at the para and meta positions of four phenyl rings on phosphorus atoms and their cationic Ru(II) complexes have also been synthesized.These BINAP-Ru(II) complexes have been used as catalysts for the asymmetric hydrogenation of various unsaturated organic compounds such as α- and β-keto esters, allylic alcohols, and α,β-unsaturated carboxylic acids in excellent diastereo- and/or enantioselectivities.Catalytic activities and stereoselectivities depend highly on reaction conditions such as solvent, temperature, and additives.Variation of halogen ligands bound to ruthenium atom and substituents on four phenyl rings of BINAP also have exerted remarkable effects on the efficiency of the catalysis.Asymmetric hydrogenation of methyl (+/-)-2-(benzamidomethyl)-3-oxobutanoate catalyzed by the species derived from 9c and 3,5-(t-Bu)2-BINAP afforded the corresponding syn-(2S,3R)-17 in 98percent de and 99percent ee.
