137226-14-3Relevant academic research and scientific papers
Convenient synthesis of monoprotected 1,2-diols
Poppe,Recseg,Novak
, p. 3993 - 4000 (2007/10/03)
Reaction of the protected glycidol derivatives (1A-C) with a wide variety of Grignard reagents (2a-h) in the presence of catalytic amount of CuCN provided the corresponding monoprotected diol derivatives (3) in a highly regioselective manner.
Higher order, mixed cyanocuprates derived from N-lithio-imidazole and pyrrole: New 'dummy' ligand alternatives in organocopper chemistry
Lipshutz,Fatheree,Hagen,Stevens
, p. 1041 - 1044 (2007/10/02)
Treatment of N-lithioimidazole or N-lithiopyrrole with CuCN followed by an organolithium leads to cuprates R(Imid)Cu(CN)Li2 and R(Pyrr)Cu(CN)Li2 which show 'higher order' reactivity relative to RCu(CN)Li.
