1372616-48-2Relevant academic research and scientific papers
Regioselective C-S bond formation accomplished by copper-catalyzed regioselective C-F substitution of perfluoroarenes with aryl thioacetates or benzyl thioacetate
Zhou, Qizhong,Zhang, Bin,Du, Tieqi,Gu, Haining,Jiang, Huajiang,Chen, Rener
experimental part, p. 4233 - 4241 (2012/07/14)
Practical and straightforward method for regioselective C-S bond formation accomplished by copper-catalyzed regioselective C-F substitution of electron-deficient perfluoroarenes with aryl thioacetates or benzyl thioacetate has been developed. Because of its high reaction efficiency, good chemoselectivity and regioselectivity, and excellent functional-group compatibility, this protocol provides a useful and operationally simple access to polyfluoroaryl thioethers used for drugs and material chemistry.
Regioselective C-S bond formation accomplished by regioselective C-F substitution of polyfluoroarenes with substituted thiophenols
Zhou, Qizhong,Zhang, Bin,Gu, Haining,Zhong, Aiguo,Du, Tieqi,Zhou, Qiong,Ye, Yuyuan,Jin, Zhengneng,Jiang, Huajiang,Chen, Rener
experimental part, p. 175 - 182 (2012/07/14)
The nucleophilic aromatic substitution reaction of pentafluorobenzene, methyl 2,3,4,5-tetrafluorobenzoic acid ester and 1,2,4,5-tetrafluorobenzene with substituted thiophenols showed good regioselectivity while pentafluorobenzene gave high yields. The com
