1372620-76-2

Upstream product

• 502-44-3 hexahydro-2H-oxepin-2-one 
• 1191-25-9 6-Hydroxyhexanoic acid 
• 1372620-70-6 (S)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)dodec-5-en-4-yloxy)(phenyl)silyl)benzene 
• 1372620-72-8 (S)-4-(tert-butyldimethylsilyloxy)dodec-5-en-1-ol 
• 1372620-74-0 C₂₈H₄₀O₂Si 
• 50889-29-7 (5-carboxypentyl)triphenylphosphonium bromide 
• 4224-70-8 6-bromohexanoic acid 

Downstream Products

• 1372620-60-4 (10R)-10-hydroxy-N-phenethyloctadecanamide 
• 1372620-80-8 (R)-10-(tert-butyldiphenylsilyloxy)-N-phenethyloctadecanamide 
• 1372620-78-4 (S)-10-(tert-butyldiphenylsilyloxy)-N-phenethyloctadeca-6,11-dienamide 

Relevant academic research and scientific papers

A new phenylethyl alkyl amide from the Ambrostoma quadriimpressum Motschulsky

A new phenylethyl alkyl amide, (10R)-10-hydroxy-N-phenethyloctadecanamide (1), was isolated from the beetle Ambrostoma quadriimpressum Motschulsky. The structure of the amide was determined by NMR and MS. The absolute configuration of compound 1 was confirmed by an asymmetric total synthesis, which was started from L-glutamic acid. The construction of the aliphatic chain was accomplished by the selective protection of the hydroxy groups and two-time implementation of the Wittig olefination reaction.