1372790-73-2Relevant academic research and scientific papers
Process for preparing styrene derivatives
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Paragraph 0046; 0047; 0048, (2014/01/07)
A process is provided which allows the synthesis of a large number of styrene derivatives with formation of C—C bonds, with use being possible of economically advantageous substrates, readily available carbon nucleophiles, and both inexpensive and environmentally unproblematic catalyst systems, permitting reaction under mild conditions and a high compatibility with functional groups on the reactants involved.
Chlorostyrenes in iron-catalyzed biaryl coupling reactions
Guelak, Samet,Jacobivonwangelin, Axel
, p. 1357 - 1361 (2012/03/26)
An effective protocol for iron-catalyzed biaryl syntheses by coupling chlorostyrenes with aryl Grignard reagents requires only mild reaction conditions and tolerates various functional groups. The underlying activation of deactivated aryl chlorides proceeds through a rate-determining coordination of the catalyst to the vinyl substituent and subsequent haptotropic migration along the conjugated πsystem to the site of C-Cl bond cleavage. Copyright
