1373170-53-6Relevant academic research and scientific papers
TIPSOTf-promoted tandem reaction through rearrangement of epoxides into aldehydes with selective alkyl migration followed by prins-type cyclization to cyclopentanes
Kodama, Takeshi,Harada, Shingo,Tanaka, Takeshi,Tachi, Yoshimitsu,Morimoto, Yoshiki
, p. 458 - 462 (2012)
The tandem reaction of trisubstituted epoxides to cyclopentanes promoted by TIPSOTf in nitromethane has been found. It consists of stereospecific rearrangement of epoxides into aldehydes accompanied with selective alkyl migration and subsequent Prins-type cyclization of the aldehydes generated to cyclopentanes. Georg Thieme Verlag Stuttgart · New York.
