1373264-73-3Relevant academic research and scientific papers
Geminally diaurated gold(I) aryls from boronic acids
Heckler, James E.,Zeller, Matthias,Hunter, Allen D.,Gray, Thomas G.
, p. 5924 - 5928 (2012/07/13)
The electrophilic [Ph3PAu]NTf2 quickly diaurates aryl boronic acids providing stable geminally diaurated complexes (see example; yellow, Au; orange, P; blue, C) that have been spectroscopically, and in some cases crystallographically
Strong electronic and counterion effects on geminal digold formation and reactivity as revealed by gold(I)-aryl model complexes
Weber, Dieter,Jones, T. David,Adduci, Laura L.,Gagne, Michel R.
, p. 2452 - 2456 (2012/04/17)
Geminal diauration of [Ph3PAu(aryl)] complexes has been investigated to model the intermediacy of geminally diaurated gold(I)-vinyl complexes in catalysis (see scheme). The results advance our understanding of the factors influencing the stability, reactivity, and dynamics of these organometallic intermediates. Copyright
