1373432-01-9Relevant academic research and scientific papers
New thiochromans via reductive cyclization of thiophenol derivatives
Niermann, André,Gr?ssel, Janine E.,Reissig, Hans-Ulrich
, p. 177 - 180 (2013)
Reductive cyclization of sulfur-containing substrates 1 and 5 with samarium diiodide afforded the corresponding thiochroman derivatives with excellent diastereoselectivities. Cyclization of 1 is facilitated by geminal dimethyl substitution, which accelera
Conjugate addition of unactivated thiols to α,β-unsaturated ketones catalyzed by a bifunctional rhenium(V)-oxo complex
Peng, Allan,Rosenblatt, Ross,Nolin, Kristine
supporting information; experimental part, p. 2712 - 2714 (2012/07/14)
ReOCl3(OPPh3)(S(CH3)2) has been found to be an efficient bifunctional catalyst for the 1,4-addition of thiols to α,β-unsaturated ketones. The addition of thiophenol derivatives and alkyl thiols proceeds under mi
