1373442-24-0

Basic information

• Product Name: (E)-methyl 3-(2-acetamido-5-bromophenyl)acrylate
• Synonyms: (E)-methyl 3-(2-acetamido-5-bromophenyl)acrylate
• CAS NO: 1373442-24-0
• Molecular Weight: 298.136
• Mol File: 1373442-24-0.mol

Chemical Properties

• CAS DataBase Reference: (E)-methyl 3-(2-acetamido-5-bromophenyl)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl 3-(2-acetamido-5-bromophenyl)acrylate(1373442-24-0)
• EPA Substance Registry System: (E)-methyl 3-(2-acetamido-5-bromophenyl)acrylate(1373442-24-0)

Safety Data

• Hazardous Substances Data: 1373442-24-0(Hazardous Substances Data)

Upstream product

• 586-78-7 para-nitrophenyl bromide 
• 67274-48-0 N-acetyl-N-(4-bromophenyl)hydroxylamine 
• 292638-85-8 acrylic acid methyl ester 
• 103-88-8 4-bromoacetanilide 

Downstream Products

• 1373442-44-4 (E)-4-bromo-2-(3-methoxy-3-oxoprop-1-en-1-yl)benzene-1-diazonium tetrafluoroborate 
• 1373442-68-2 (2E,2'E)-dimethyl 3,3'-(4-bromo-1,2-phenylen)diacrylate 

Relevant articles and documents

Rhodium(III)-catalyzed internal oxidative coupling of N-hydroxyanilides with alkenes via C-H activation

Abstract Described herein is an efficient new method for ortho-olefination of anilides in the presence of AgSbF6 and NaOAc via rhodium(III)-catalyzed internal oxidative C-H bond activation based on hydroxyl as directing and oxidative group. A range of alkenes and functional groups on acetanilides is supported and a possible mechanism is proposed according to the experimental results.

Selective arene functionalization through sequential oxidative and non-oxidative Heck reactions

A sequence of acetamide directed oxidative Heck reaction and deacetylation-diazotation-Heck coupling allows the traceless removal of the acetamide group and its dual exploitation as a catalyst directing group and a leaving group. The Royal Society of Chem