137351-83-8

Upstream product

• 7162-15-4 methyl phenylphosphinate 
• 4969-33-9 3-O-acetyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hex-5-enofuranose 
• 137012-85-2 (5R and 5S)-3-O-acetyl-5,6-dideoxy-1,2-O-isopropylidene-5-<(R and S)-(methoxy)phenylphosphinyl>-6-nitro-α-xylo-hexofuranose 

Downstream Products

• 137012-91-0 5-<(R)-phenyl-phosphino>-β-D-glucopyranose 
• 137012-87-4 (5R and 5S)-3-O-acetyl-5-deoxy-1,2-O-isopropylidene-5-<(R and S)-(methoxy)phenylphosphinyl>-6-O-(tetrahydro-2-pyranyl)-α-D-xylo-hexofuranose 
• 137012-88-5 (3aR,5S,6R,6aR)-2,2-Dimethyl-5-[1-phenylphosphanyl-2-(tetrahydro-pyran-2-yloxy)-ethyl]-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol 
• 137012-86-3 (5R and 5S)-3-O-acetyl-5-deoxy-1,2-O-isopropylidene-5-<(R and S)-(methoxy)phenylphosphinyl>-α-D-xylo-hexofuranose 

Relevant academic research and scientific papers

Synthesis of 5-Deoxy-5-phenylphosphino- and 5-Phenylphosphinyl-D-glucopyranoses

(5R and 5S)-3-O-Acetyl-5-deoxy-1,2-O-isopropylidene-5--6-O-(tetrahydro-2-pyranyl)-α-D-xylo-hexofuranoses (7) were prepared from 3-O-acetyl-5,6-dideoxy-6-nitro-α-D-xylo-hex-5-enofuranose in 4 steps.Reduction of 7 with sodium dihy