137379-56-7

Upstream product

• 108-30-5 succinic acid anhydride 
• 3963-62-0 2,2-Diphenylethylamine 

Downstream Products

• 573986-14-8 N¹-(12-aminododecyl)-N⁴-(2,2-diphenylethyl)succinamide 
• 1020416-93-6 N-butyl-N'-(2,2-diphenylethyl)succinamide 
• 1226910-38-8 C₄₉H₆₂N₄O₅ 
• 573986-23-9 (Z)-But-2-enedioic acid (2,2-diphenyl-ethyl)-amide {12-[3-(2,2-diphenyl-ethylcarbamoyl)-propionylamino]-dodecyl}-amide 
• 891849-25-5 N-(2,2-diphenyl-ethyl)-N'-[4-(10-isobutyl-2,4-dioxo-7-trifluoromethyl-4,10-dihydro-2H-benzo[g]pteridin-3-ylmethyl)-phenyl]-succinamide 
• 342634-60-0 N-{12-[5,8-di(tert-butyl)-1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl]dodecyl}-N'-(2,2-diphenylethyl)-succinamide 
• 575450-10-1 N-{2-[5,8-di(tert-butyl)-1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl]ethyl}-N'-(2,2-diphenylethyl)-succinamide 

Relevant academic research and scientific papers

Electrochemically switchable hydrogen-bonded molecular shuttles

A series of [2]rotaxanes containing succinamide and naphthalimide hydrogen-bonding stations for a benzylic amide macrocycle is described. Electrochemical reduction and oxidation of the naphthalimide group alters its ability to form hydrogen bonds to the m

Infrared study of intercomponent interactions in a switchable hydrogen-bonded rotaxane

The macrocycle in rotaxane 1 is preferentially hydrogen bonded to the succinamide station in the neutral form, but can be moved to the naphthalimide station by one-electron reduction of the latter. The hydrogen bonding between the amide NH groups of the macrocycle and the C=O groups in the binding stations in the thread was studied with IR spectroscopy in different solvents in both states. In addition, the solvent effect on the vibrational frequencies was analyzed; a correlation with the solvent acceptor number (AN) was observed. The conformational switching upon reduction could be detected by monitoring the hydrogen-bond-induced shifts of the v(CO) frequencies of the C=O groups of the succinamide and the reduced naphthalimide stations. The macrocycle was found to shield the encapsulated station from the solvent: wavenumbers of v(CO) bands of the C=O groups residing inside the macrocycle cavity remain unaffected by the solvent polarity.

Remarkable positional discrimination in bistable light- and heat-switchable hydrogen-bonded molecular shuttles

A tale of two stations: Molecular shuttles, in which a macrocyclic unit can move between two stations over a relatively large distance (1.5 nm), exhibit bistability that can be induced using either light or heat as stimuli, and exhibit large required vari