1373875-32-1Relevant academic research and scientific papers
Benzylic ethers as arylcarboxy surrogates in substrate directed ortho C-H functionalisation catalysed by copper
Khatun, Nilufa,Banerjee, Arghya,Santra, Sourav Kumar,Ali, Wajid,Patel, Bhisma K.
, p. 36461 - 36466 (2015)
A copper catalysed ortho-benzoxylation of 2-arylpyridines has been accomplished using benzylic ethers as the alternative arylcarboxy sources (ArCOO-) via sp2 C-H bond activation. The use of the Pd/TBHP catalytic system is reported to install an
Terminal aryl alkenes and alkynes as arylcarboxy surrogates toward o -Benzoxylation of 2-phenylpyridine catalyzed by copper
Rout, Saroj Kumar,Guin, Srimanta,Gogoi, Anupal,Majji, Ganesh,Patel, Bhisma K.
supporting information, p. 1614 - 1617 (2014/04/17)
A variety of styrenes and phenylacetylenes serve as excellent arylcarboxy sources in bringing about substrate directed o-benzoxylation of 2-phenylpyridine derivatives catalyzed by Cu(II) in the presence of TBHP. This reaction proceeds via formation of phenylglyoxal followed by decarbonylation to benzoyl radical/benzaldehyde which acts as the arylcarboxy source.
'Ligand-free' palladium-catalyzed direct C-H bond oxidative acyloxylation of 2-arylpyridines with aromatic carboxylic acids
Hu, Chao-Jun,Zhang, Xiao-Hong,Ding, Qiu-Ping,Lv, Ting,Ge, Shao-Peng,Zhong, Ping
scheme or table, p. 2465 - 2468 (2012/06/01)
A palladium-catalyzed direct C-H bond oxidative acyloxylation of 2-arylpyridines with aromatic carboxylic acids is described. Several 2-arylpyridines derivatives and aromatic carboxylic acids participate in the reaction, providing a series of mono-acyloxy
