137401-55-9

Basic information

• Product Name: cis-2-hydroxymethyl-5-phenyl-1-p-toluenesulfonylpyrrolidine
• Synonyms: cis-2-hydroxymethyl-5-phenyl-1-p-toluenesulfonylpyrrolidine
• CAS NO: 137401-55-9
• Molecular Weight: 331.436
• Mol File: 137401-55-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: cis-2-hydroxymethyl-5-phenyl-1-p-toluenesulfonylpyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: cis-2-hydroxymethyl-5-phenyl-1-p-toluenesulfonylpyrrolidine(137401-55-9)
• EPA Substance Registry System: cis-2-hydroxymethyl-5-phenyl-1-p-toluenesulfonylpyrrolidine(137401-55-9)

Safety Data

• Hazardous Substances Data: 137401-55-9(Hazardous Substances Data)

Upstream product

• 3240-29-7 1-Phenylpent-4-en-1-one 
• 98-59-9 p-toluenesulfonyl chloride 
• 137401-49-1 N-1-phenyl-N-tosylhexa-4,5-dienylamine 
• 780-25-6 N-benzylidene benzylamine 
• 137401-52-6 rac-(2R,5S)-1-[(4-methylphenyl)sulfonyl]-2-phenyl-5-vinylpyrrolidine 

Downstream Products

• 137401-56-0 cis-5-phenyl-N-tosylpyrrolidin-2-ylmethyl 4 bromobenzoate 

Relevant articles and documents

Synthesis of Functionalized Pyrrolines via Microwave-Promoted Iminyl Radical Cyclizations

O-Phenyloximes tethered to alkenes undergo 5-exo-trig iminyl radical cyclizations upon microwave irradiation. Trapping of the resulting cyclic radicals results in C-C, C-N, C-O, C-S, or C-X bond formation. Allylic sulfides undergo a tandem cyclization-thi

Stereoselectivity in Electrophile-Mediated Cyclisations. AgI-Catalysed Synthesis of Disubstituted Pyrrolidines; Crystal Structure of cis-5-Phenyl-N-tosylpyrrolidin-2-ylmethyl 4-Bromobenzoate

A series of phenyl-substituted allenic sulphonamides 5, 6 and 7 have been prepared and shown to undergo AgI-catalysed cyclisation to give the corresponding 2,5-, 2,4- and 2,3-disubstituted N-sulphonylpyrrolidines 8, 9, and 10 respectively.The i