137407-31-9Relevant articles and documents
Synthesis and physical properties of ferrocene derivatives (XXIII): Phase transition and unique molecular structure of monosubstituted ferrocene derivatives
Nakamura, Naotake,Hiro, Kazuya,Nishikawa, Masako,Okabe, Takashi,Uno, Kenjiro
, p. 122 - 131 (2010)
The monosubstituted ferrocene derivatives, -[4-(4-methoxyphenoxycarbonyl) phenoxy]alkoxycarbonyl ferrocene, were synthesized in order to compare the liquid crystallinity to that of disubstituted ferrocene derivatives, 1,1'-bis[-[4-(4-methoxy-phenoxycarbonyl)phenoxy]alkoxycarbonyl]ferrocene. Some of the monosubstituted ferrocene derivatives containing relatively longer flexible spacer showed the liquid crystalline phase, nematic and/or smectic phases. The crystal structure of 2-[4-(4-methoxyphenoxycarbonyl)phenoxy] ethoxycarbonyl ferrocene was determined by X-ray diffraction method using a single crystal. The molecular structure revealed a bent structure that is almost a half of "Z" shaped molecular structure of 1,1'-bis[2-[4-(4- methoxyphenoxycarbonyl)phenoxy]ethoxycarbonyl]ferrocene.
Vinylsulfone derivative, liquid crystal composition comprising the same and compensation film using the same liquid crystal composition
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Page/Page column 19-22, (2011/04/18)
Disclosed are a vinylsulfone derivative, a liquid crystal composition comprising the same, and a compensation film for a liquid crystal display device using the same liquid crystal composition. More particularly, the vinylsulfone derivative is a liquid cr