137410-26-5

Basic information

• Product Name: (2S,3R,4E)-2-azido-1,3-dibenzyloxyoctadeca-4-ene
• Synonyms: (2S,3R,4E)-2-azido-1,3-dibenzyloxyoctadeca-4-ene
• CAS NO: 137410-26-5
• Molecular Weight: 505.744
• Mol File: 137410-26-5.mol

Chemical Properties

• CAS DataBase Reference: (2S,3R,4E)-2-azido-1,3-dibenzyloxyoctadeca-4-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4E)-2-azido-1,3-dibenzyloxyoctadeca-4-ene(137410-26-5)
• EPA Substance Registry System: (2S,3R,4E)-2-azido-1,3-dibenzyloxyoctadeca-4-ene(137410-26-5)

Safety Data

• Hazardous Substances Data: 137410-26-5(Hazardous Substances Data)

Upstream product

• 603-35-0 triphenylphosphine 
• 112-71-0 1-Bromotetradecane 
• 25791-20-2 (n-tetradecyl)triphenylphosphonium bromide 
• 185681-39-4 Methanesulfonic acid (1R,2R,3S)-2-benzyloxy-1-benzyloxymethyl-3-methanesulfonyloxy-pent-4-enyl ester 
• 185681-38-3 4,6-di-O-benzyl-1,2-dideoxy-D-xylo-hex-1-enitol 
• 16054-77-6 3,5-di-O-benzyl-D-xylofuranose 
• 15890-72-9 laurylmagnesium bromide 
• 185681-40-7 (2R,3R,4E)-1,3-Di-O-benzyl-2-O-methylsulfonyloctadec-4-ene-1,2,3-triol 

Downstream Products

• 185681-41-8 (E)-(1S,2R)-2-Benzyloxy-1-benzyloxymethyl-heptadec-3-enylamine 
• 148289-52-5 (2S,3R)-2-amino-1,3-(dibenzyloxy)-octadeca-4-ene 
• 764-22-7 (2S,3R)-2-amino-1,3-octadecanediol 
• 123-78-4 (2S,3R,4E)-2-amino-4-octadecene-1,3-diol 
• 54336-64-0 (2S,3R,4E)-2-(N-stearoylamino)-4-octadecene-1,3-diol 

Relevant articles and documents

Stereoselective synthesis of N,O,O,O-tetraacetyl-D-ribo-phytosphingosine, N,O,O-triacetyl-D-erythro-sphingosine and N,O,O-triacetyl sphingonine from a common chiral intermediate derived from D-mannitol

An efficient protocol for the stereoselective synthesis of tetraacetyl-D-ribo-hytosphingosine, triacetyl-D-erythro-sphingosine and triacetyl sphinganine has been devised from a common chiral intermediate derived from commercially available D-mannitol. The key steps involved are Sharpless epoxidation, Miyashita C(2) selective endo mode azide opening of 2,3-epoxy alcohol, and selective E-Wittig olefination. ARKAT-USA, Inc.

A facile stereoselective synthesis of sphingosine and ceramide

Flexible syntheses of sphingosine and ceramide were achieved by using D-xylose as the chiral pool and a CuCN-catalyzed allylic alkylation reaction of a dimesylate 8 for chain elongation with concomitant control of an E configuration of the double bond. VCH Verlagsgesellschaft mbH, 1996.