15890-72-9 Usage
Description
DODECYLMAGNESIUM BROMIDE, also known as dodecylmagnesium bromide, is an organomagnesium compound that is a part of the Grignard reagent family. It is a colorless to light yellow liquid with enhanced energy efficiency. DODECYLMAGNESIUM BROMIDE is characterized by its chemical properties, which make it suitable for various applications in different industries.
Uses
Used in Organic Chemistry:
DODECYLMAGNESIUM BROMIDE is used as a Grignard reagent for facilitating various organic reactions, particularly in the synthesis of complex organic molecules. Its ability to form carbon-carbon and carbon-heteroatom bonds makes it a versatile tool in organic chemistry.
Used in Green Chemistry:
DODECYLMAGNESIUM BROMIDE is used as a Grignard reagent in greener solvents, such as 2-methyltetrahydrofuran (2-MeTHF). This application aims to reduce the environmental impact of chemical reactions by using more sustainable and less toxic solvents.
Used in Biomass-Derived Solvent Applications:
DODECYLMAGNESIUM BROMIDE is used as a catalyst in the production of 2-Methyltetrahydrofuran (2-MeTHF), a biomass-derived solvent with broad application in organic chemistry. This use contributes to the development of sustainable and eco-friendly chemical processes.
Check Digit Verification of cas no
The CAS Registry Mumber 15890-72-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,8,9 and 0 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 15890-72:
(7*1)+(6*5)+(5*8)+(4*9)+(3*0)+(2*7)+(1*2)=129
129 % 10 = 9
So 15890-72-9 is a valid CAS Registry Number.
InChI:InChI=1/C12H25.BrH.Mg/c1-3-5-7-9-11-12-10-8-6-4-2;;/h1,3-12H2,2H3;1H;/q;;+1/p-1/rC12H25BrMg/c1-2-3-4-5-6-7-8-9-10-11-12-14-13/h2-12H2,1H3
15890-72-9Relevant articles and documents
Chromium(II)-Catalyzed Diastereoselective and Chemoselective Csp2-Csp3 Cross-Couplings Using Organomagnesium Reagents
Li, Jie,Ren, Qianyi,Cheng, Xinyi,Karaghiosoff, Konstantin,Knochel, Paul
supporting information, p. 18127 - 18135 (2019/11/19)
A simple protocol for performing chromium-catalyzed highly diastereoselective alkylations of arylmagnesium halides with cyclohexyl iodides at ambient temperature has been developed. Furthermore, this ligand-free CrCl2 enables efficient electrophilic alkenylations of primary, secondary, and tetiary alkylmagnesium halides with readily available alkenyl acetates. Moreover, this chemoselective C-C coupling reaction with stereodefined alkenyl acetates proceeds in a stereoretentive fashion. A wide range of functional groups on alkyl iodides and alkenyl acetates are well tolerated, thus furnishing functionalized Csp2-Csp3 coupling products in good yields and high diastereoselectivity. Detailed mechanistic studies suggest that the in situ generated low-valent chromium(I) species might be the active catalyst for these Csp2-Csp3 cross-couplings.
Novel fluorescent quater- and quinquifurans: Syntheses and photophysical properties
Kauffman, Joel M.,Moyna, Guillermo
, p. 981 - 988 (2007/10/03)
In the quest for fast fluors for use in waveshifting polystyrene fibers, symmetrical oligofurans were investigated. Furan moieties were coupled by means of the Ullmann Reaction or by palladium-catalyzed unsymmetrical coupling; the latter gave higher yields. While the benzoxazole-terminated quater- and quinquifurans we prepared were both stable and fast, exhibiting a green fluorescence and decay times of about 2.4 nsec, they were inferior to other types of fluors in solubility and emission intensity when incorporated into polystyrene.
0.5 M in 2-
