13743-24-3Relevant academic research and scientific papers
A study on the deoxygenation of trialkyl-, dialkyl-phenyl- and alkyl-diphenyl phosphine oxides by hydrosilanes
Kovács, Tamara,Urbanics, Anita,Csatlós, Flóra,Keglevich, Gy?rgy
, (2017)
The deoxygenation of 1-alkyl-3-methyl-3-phospholene 1-oxides, which may be regarded as trialkyl phosphine oxides (R3PO), and the reduction of dialkyl-phenylphosphine oxides (R2PhPO) and methyl-diphenylphosphine oxide (MePh2PO) have been elaborated by applying user-friendly silanes, such as tetramethyldisiloxane (>SiH–O–HSin) under solvent-free, catalyst-free, and microwave (MW)-assisted conditions. New silanes of type Ar2SiH2, alkyl2SiH2, and Ar3SiH were also applied in a few cases. The reactivity of the phosphine oxides and the silanes could be mapped on the basis of our experimental data.
