137433-86-4Relevant academic research and scientific papers
Regioselective Alkyl and Alkynyl Substitution Reactions of Epoxy Alcohols by the Use of Organoaluminum Ate Complexes: Regiochemical Reversal of Nucleophilic Substitution Reactions
Sasaki, Minoru,Tanino, Keiji,Miyashita, Masaaki
, p. 1765 - 1767 (2007/10/03)
(matrix presented) Unprecedented nucleophilic substitution reactions of 2,3-epoxy-1-alkanols with alkyl- and alkynylaluminum ate complexes have been studied and demonstrated to occur at the C2 position with extremely high stereoselectivity, i.e., with exa
Pheromone Synthesis, CXXXV. Synthesis of (4R,5R,6S,7E,9E)-4,6,8-Trimethyl-7,9-undecadien-5-ol and Its Antipode, the Female Specific Compound of the Woodroach Cryptocercus punctulatus
Mori, Kenji,Itou, Masamichi
, p. 87 - 94 (2007/10/02)
(4R,5R,6S,7E,9E)-4,6,8-Trimethyl-7,9-undecadien-5-ol (1) and its antipode 1', the female specific compound of the woodroach Cryptocercus punctulatus, were synthesized by starting from methyl (R)-3-hydroxy-2-methylpropanoate (C). Key Words: Chiral centers,
