1374337-13-9

Basic information

• Product Name: C₂₃H₂₂OSi
• Synonyms: C₂₃H₂₂OSi
• CAS NO: 1374337-13-9
• Molecular Weight: 342.513
• Mol File: 1374337-13-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₂₃H₂₂OSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₃H₂₂OSi(1374337-13-9)
• EPA Substance Registry System: C₂₃H₂₂OSi(1374337-13-9)

Safety Data

• Hazardous Substances Data: 1374337-13-9(Hazardous Substances Data)

Upstream product

• 2398-37-0 3-methoxyphenyl bromide 
• 17903-36-5 1-bromo-4-methoxylphenyltrimethylsilane 
• 501-65-5 diphenyl acetylene 
• 17876-90-3 3-trimethylsilylanisol 
• 556812-41-0 4-methoxy-2-(trimethylsilyl)phenyl triflate 

Relevant articles and documents

Palladium-catalyzed cleavage of the Me-Si bond in ortho-trimethylsilyl aryltriflates: Synthesis of benzosilole derivatives from ortho-trimethylsilyl aryltriflates and alkynes

An efficient Pd-catalyzed cleavage of the Me-Si bond in ortho-trimethylsilyl aryltriflates was realized and synthetically applied. Most of the commercially available ortho-trimethylsilyl aryltriflates could undergo the Pd-catalyzed intermolecular coupling with alkynes via cleavage of the Me-Si bond, which represents a new reaction pattern of ortho-trimethylsilyl aryltriflates. Potassium bromide (KBr) was found effective for this process. A variety of benzosilole derivatives were thus generated in high yields. The Royal Society of Chemistry 2013.