137438-50-7

Basic information

• Product Name: (1-TERT-BUTYL-BUT-3-ENYLOXYMETHYL)-BENZENE
• Synonyms: (1-TERT-BUTYL-BUT-3-ENYLOXYMETHYL)-BENZENE
• CAS NO: 137438-50-7
• Molecular Formula: C₁₅H₂₂O
• Molecular Weight: 218.33458
• Mol File: 137438-50-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 277.4±19.0 °C(Predicted)
• Appearance: /
• Density: 0.910±0.06 g/cm3(Predicted)
• CAS DataBase Reference: (1-TERT-BUTYL-BUT-3-ENYLOXYMETHYL)-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: (1-TERT-BUTYL-BUT-3-ENYLOXYMETHYL)-BENZENE(137438-50-7)
• EPA Substance Registry System: (1-TERT-BUTYL-BUT-3-ENYLOXYMETHYL)-BENZENE(137438-50-7)

Safety Data

• Hazardous Substances Data: 137438-50-7(Hazardous Substances Data)

Usage

General Description

(1-Tert-Butyl-But-3-Enyloxymethyl)-Benzene is a chemical compound with the molecular formula C15H22. It is a colorless liquid and is primarily used as an intermediate in the synthesis of various organic compounds. It is often utilized in the production of fine chemicals, pharmaceuticals, and agrochemicals. The compound possesses potential for use in a variety of industries due to its versatile nature and reactivity. However, it is important to handle this chemical with caution as it may pose risks to human health and the environment if not properly managed and disposed of.

Upstream product

• 630-19-3 pivalaldehyde 
• 100-51-6 benzyl alcohol 
• 762-72-1 allyl-trimethyl-silane 
• 133797-68-9 2,2-dimethylpropionaldehyde dibenzyl acetal 
• 14642-79-6 benzyloxy-trimethylsilane 

Relevant articles and documents

Bronsted acid-catalyzed three-component hosomi-sakurai reactions

Aldehydes react with silyl ethers or the corresponding alcohols and allylsilanes in the presence of catalytic amounts of 2,4-dinitrobenzenesulfonic acid (DNBA) to provide a wide range of homoallylic ethers in moderate to high yields.

Iron(III) chloride-catalyzed convenient one-pot synthesis of homoallyl benzyl ethers starting from aldehydes

(Matrix presented) Iron(III) chloride-catalyzed effective allylation reactions of acetals with allyltrimethylsilane proceeded smoothly in high to excellent yields. In addition, this method could be applied to the one-pot synthesis of homoallyl benzyl ethe

The Silyl Modified Sakurai (SMS) reaction. An efficient and versatile one-pot synthesis of homoallylic ethers

An efficient and versatile preparation of homoallylic ethers from trimethylsilyl ethers, allyltrimethylsilane and carbonyl compounds is described. Some preliminary experiments, aimed at controlling the diastereofacial selection in the SMS reaction, are al