137441-14-6

Upstream product

• 137208-48-1 (6R,7aR)-8,8-dimethylhexahydro-2H-3a,6-methanobenzo[d]-oxazol-2-one 
• 100-52-7 benzaldehyde 
• 137208-49-2 N-propionyl-(1S,5R,7R)-10,10-dimethyl-3-oxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane 

Downstream Products

• 76549-03-6 methyl (2S,3S)-3-hydroxy-2-methyl-3-phenylpropanoate 

Relevant academic research and scientific papers

Asymmetric aldol reactions: A novel model for switching between chelation- and non-chelation-controlled aldol reactions

A new camphor-based N-propionyloxazolidinethione provides remarkable levels of asymmetric induction for both chelation- and non-chelation-controlled aldol processes. While the aldol condensation of the derived di-n-butylboryl enolate with various aldehyde

A Superior Chiral Auxiliary in Aldol Condensations: Camphor-Based Oxazolidone

The aldol reactions from boron enolate derived from camphor-based N-propionyloxazolidone exhibit exceptionally high stereoselection.The initial aldol adducts from lithium mediated reactions equilibrate to furnish erythro isomers.Erythro selection is contr