1374647-36-5

Basic information

• Product Name: (E)-1-(4-bromobut-2-en-2-yl)-2-methylbenzene
• Synonyms: (E)-1-(4-bromobut-2-en-2-yl)-2-methylbenzene
• CAS NO: 1374647-36-5
• Molecular Weight: 225.128
• Mol File: 1374647-36-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1-(4-bromobut-2-en-2-yl)-2-methylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(4-bromobut-2-en-2-yl)-2-methylbenzene(1374647-36-5)
• EPA Substance Registry System: (E)-1-(4-bromobut-2-en-2-yl)-2-methylbenzene(1374647-36-5)

Safety Data

• Hazardous Substances Data: 1374647-36-5(Hazardous Substances Data)

Upstream product

• 1174270-30-4 (E)-3-(o-tolyl)but-2-en-1-ol 
• 100994-06-7 (E)-ethyl 3-(2-methylphenyl)-but-2-enoate 
• 577-16-2 2-Methylacetophenone 
• 100994-06-7 EtO₂CCHC(Me)(o-MeC₆H₄) 

Downstream Products

• 53109-16-3 2-phenyl-2-(E/Z)-octene 
• 1374647-46-7 (-)-1-methyl-2-(3-methylhept-1-en-3-yl)benzene 
• 1374647-48-9 (-)-1-methyl-2-(3-methylnon-1-en-3-yl)benzene 

Relevant articles and documents

Transition-Metal-Free Formylation of Allylzinc Reagents Leading to α-Quaternary Aldehydes

The first example of formylation of allylzinc reagents using S-phenyl thioformate is presented. The reaction proceeded under mild conditions without any transition-metal catalyst, forming quaternary carbon centers with reactive functionalities, such as formyl and vinyl groups. Moreover, Barbier-type formylation of an allylic bromide with a sterically demanding thioformate was achieved. As a preliminary result, asymmetric formylation was conducted using a menthol-derived chiral thioformate.