1374869-43-8Relevant articles and documents
A Practical Aryliodine(I/III) Catalysis for the Vicinal Diamination of Styrenes
Cots, Eric,Flores, Andrea,Romero, R. Martín,Mu?iz, Kilian
, p. 3028 - 3031 (2019/03/26)
2,6-Disubstituted iodoarenes bearing amide-functionalized side arms are reported as new structures in redox-active iodine(I/III) catalysis. In combination with bis-sulfonimides as nitrogen sources and 3-chloroperbenzoic acid (mCPBA) as benign terminal oxi
Enantioselective metal-free diamination of styrenes
Roeben, Caren,Souto, Jose A.,Gonzalez, Yolanda,Lishchynskyi, Anton,Muniz, Kilian
supporting information; experimental part, p. 9478 - 9482 (2011/11/06)
Metal-free and asymmetric: The first enantioselective diamination of styrenes simply requires a chiral hypervalent iodine(III) reagent as an oxidant and bismesylimide as a nitrogen source (see scheme, Ms=methanesulfonyl). The reaction proceeds under mild conditions and with high enantiomeric excess.