1375475-50-5Relevant academic research and scientific papers
Asymmetric synthesis of allylic amines: Via hydroamination of allenes with benzophenone imine
Xu, Kun,Wang, Yu-Hsuan,Khakyzadeh, Vahid,Breit, Bernhard
, p. 3313 - 3316 (2016)
Rhodium-catalyzed highly regio- and enantioselective hydroamination of allenes is reported. Exclusive branched selectivities and excellent enantioselectivities were achieved applying a rhodium(i)/Josiphos catalyst. This method permits the practical synthesis of valuable α-chiral allylic amines using benzophenone imine as ammonia carrier.
Direct, enantioselective iridium-catalyzed allylic amination of racemic allylic alcohols
Lafrance, Marc,Roggen, Markus,Carreira, Erick M.
supporting information; experimental part, p. 3470 - 3473 (2012/06/01)
The direct route: Iridium-catalyzed direct conversion of branched allylic alcohols into enantioenriched branched primary allylic amines is highly regio- and enantioselective (see scheme; coe=cyclooctene). Copyright
