1375478-75-3

Upstream product

• 1375478-65-1 C₁₈H₂₆O₄ 
• 1375478-66-2 C₁₅H₂₂O₄ 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 36326-38-2 ethyl (R,Z)-3-(2′,2′-dimethyl-1′,3′-dioxolan-4′-yl)acrylate 
• 928-90-5 5-hexyl-1-ol 
• 1375478-67-3 (3R,4R)-4,5-bis((tert-butyldimethylsilyl)oxy)-3-isopropylpentyl benzoate 
• 1375478-64-0 (R)-3-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-4-methylpentan-1-ol 
• 1375478-69-5 (3R,4R)-4-((tert-butyldimethylsilyl)oxy)-3-isopropyl-5-oxopentyl benzoate 
• 1375478-71-9 (E)-tert-butyl((6-iodohept-5-en-1-yl)oxy)diphenylsilane 
• 1375478-63-9 ethyl (R)-3-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-4-methylpentanoate 
• 1375478-68-4 (3R,4R)-4-((tert-butyldimethylsilyl)oxy)-5-hydroxy-3-isopropylpentyl benzoate 

Downstream Products

• 1375478-77-5 (4R,5R,6R)-5-((tert-butyldimethylsilyl)oxy)-6-((E)-7-((tert-butyldiphenylsilyl)oxy)hept-2-en-2-yl)-4-isopropyltetrahydro-2H-pyran-2-one 

Relevant academic research and scientific papers

Total synthesis of (-)-dendrobine

Cascading to alkaloids: An 18-step total synthesis of (-)-dendrobine is based on a reaction cascade with a key amine group (see scheme, Bn=benzyl). The amine is the initiator of the cascade and provides an efficient method for installing the stereocenters at C11 and C3. The overall transformation occurs stereoselectively only when the conversion is carried out without the isolation of intermediates. Copyright