1375536-71-2Relevant academic research and scientific papers
Silver-Catalyzed anti-Markovnikov Hydroboration of C-C Multiple Bonds
Wang, Yan,Guan, Rui,Sivaguru, Paramasivam,Cong, Xuefeng,Bi, Xihe
supporting information, p. 4035 - 4038 (2019/06/14)
A simple silver salt (AgOAc)-catalyzed anti-Markovnikov-selective hydroboration of alkenes, 1,3-dienes, and alkynes with pinacolborane (HBpin) has been described. This strategy provides an efficient and practical method to access various alkyl-, allyl-, a
Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: Synthesis of homoallylic boronic esters
Li, Chunsheng,Li, Meng,Li, Jianxiao,Wu, Wanqing,Jiang, Huanfeng
supporting information, p. 66 - 69 (2017/12/27)
A palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane to afford the corresponding homoallylic organoboronic esters with moderate to excellent yields is reported. This novel transformation provides an efficient strategy for the construction of homoallylic organoboronic esters in one step with a broad substrate scope. It is proposed that the palladium-catalyzed oxidative allylic C-H bond activation process may be involved in the catalytic cycle.
Cross coupling between sp3-carbon and sp3-carbon using a diborylmethane derivative at room temperature
Endo, Kohei,Ohkubo, Takahiro,Ishioka, Takafumi,Shibata, Takanori
experimental part, p. 4826 - 4831 (2012/07/30)
A novel example of the Suzuki-Miyaura cross-coupling reaction between sp3-carbon and sp3-carbon is described. The reaction of a diborylmethane derivative with allyl halides or benzyl halides proceeded efficiently in the presence of appropriate Pd-catalysts at room temperature. The present approaches provide functionalized homoallylboronates and alkylboronates with excellent regio- and chemoselectivities.
