1745-18-2

Basic information

• Product Name: 3-(4-CHLOROPHENYL)-1-PROPENE
• Synonyms: 3-(4-CHLOROPHENYL)-1-PROPENE;3-(4-CHLOROPHENYL)PROP-1-ENE;4-(PROP-2-EN-1-YL)CHLOROBENZENE
• CAS NO: 1745-18-2
• Molecular Formula: C₉H₉Cl
• Molecular Weight: 152.62
• Mol File: 1745-18-2.mol
• Article Data: 39

Chemical Properties

• Boiling Point: 195°C at 760 mmHg
• Flash Point: 71.3°C
• Appearance: /
• Density: 1.046g/cm³
• Vapor Pressure: 0.602mmHg at 25°C
• Refractive Index: 1.53
• CAS DataBase Reference: 3-(4-CHLOROPHENYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-CHLOROPHENYL)-1-PROPENE(1745-18-2)
• EPA Substance Registry System: 3-(4-CHLOROPHENYL)-1-PROPENE(1745-18-2)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 1745-18-2(Hazardous Substances Data)

Usage

General Description

3-(4-Chlorophenyl)-1-propene, also known as 4-chlorostyrene, is a chemical compound with the formula C9H9Cl. It is a colorless to pale yellow liquid with a sharp odor, and it is insoluble in water but soluble in organic solvents. 4-chlorostyrene is used primarily as an intermediate in the synthesis of various chemicals, including pharmaceuticals, agrochemicals, and dyes. It is also used in the production of polymer resins and as a monomer for copolymers. Additionally, 4-chlorostyrene is a potential environmental contaminant and should be handled and disposed of with care.

InChI:InChI=1/C9H9Cl/c1-2-3-8-4-6-9(10)7-5-8/h2,4-7H,1,3H2

Upstream product

• 10152-76-8 allylmethyl sulfide 
• 2028-74-2 p-chlorobenzenediazonium chloride 
• 5296-64-0 allyl phenyl thioether 
• 66230-04-4 esfenvalerate 
• 591-87-7 Allyl acetate 
• 14064-15-4 (4-chlorophenyl)trimethylstannane 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 106-95-6 allyl bromide 
• 1404227-24-2 2-(4-chlorophenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione 
• 106-39-8 bromochlorobenzene 
• 74472-22-3 allyl tert-butyldimethylsilane 
• 106-47-8 4-chloro-aniline 
• 17898-21-4 triethylallylsilane 
• 33558-75-7 allyl(chloromethyl)dimethylsilane 

Downstream Products

• 60691-90-9 3-bromo-1-(p-chlorophenyl)-1-propene 
• 106897-83-0 2-(4-allylphenyl)propionic acid 
• 1879-53-4 E-1-(4-chlorophenyl)-1-propene 
• 170938-14-4 (E)-3-(4-chlorophenyl)allyl acetate 
• 42175-12-2 butyl (E)-4-chlorocinnamate 
• 702-10-3 1-(4′-chlorophenyl)-2-propanol 
• 6285-05-8 4'-chloropropiophenone 
• 1616842-56-8 (E)-1-(4-chlorophenyl)-3-(2,3,5,6-tetrafluoro-4-methoxyphenyl)prop-1-ene 
• 1616842-57-9 1-(3-(4-chlorophenyl)propyl)-2,3,5,6-tetrafluoro-4-methoxybenzene 
• 1289638-90-9 (E)-1-[3-(4-chlorophenyl)allyl]-2,3,4,5,6-pentafluorobenzene 

Relevant articles and documents

REACTION OF ARYL- AND VINYLSTANNANES WITH ALLYL ACETATE IN THE PRESENCE OF TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0)

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Manganese catalyzed dehydrogenative silylation of alkenes: Direct access to allylsilanes

Dehydrogenative silylation of alkenes with silanes to produce allylsilanes is achieved through manganese catalysis with a wide scope of substrate tolerance. This transformation involves silane radicals initiated by manganese complex without additional oxidant additives. It offers a general, convenient and practical protocol with excellent functional group compatibility and gram-scale capacity for the modular synthesis of allylsilanes.

Palladium-catalyzed tandem isomerization/hydrothiolation of allylarenes

Herein we report a tandem olefin migration/hydrothiolation of allyl benzenes facilitated by an in situ generated palladium hydride. A catalyst system composed of palladium acetate and bidentate ligand dtbpx (1,2-bis(di-tert-butylphosphinomethyl)benzene in the presence of catalytic amounts of triflic acid led to the tandem transformation, which furnished benzylic thioethers. The reaction exhibits high regioselectivity and can be conducted under mild conditions. The robustness of the catalyst is displayed through reactions with coordinating thiols.