137557-26-7

Basic information

• Product Name: 8-Methyl-3-(3-nitro-phenyl)-1-oxa-2,4-diaza-spiro[4.5]dec-2-en-4-ylamine
• Synonyms: 8-Methyl-3-(3-nitro-phenyl)-1-oxa-2,4-diaza-spiro[4.5]dec-2-en-4-ylamine
• CAS NO: 137557-26-7
• Molecular Weight: 290.322
• Mol File: 137557-26-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 8-Methyl-3-(3-nitro-phenyl)-1-oxa-2,4-diaza-spiro[4.5]dec-2-en-4-ylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 8-Methyl-3-(3-nitro-phenyl)-1-oxa-2,4-diaza-spiro[4.5]dec-2-en-4-ylamine(137557-26-7)
• EPA Substance Registry System: 8-Methyl-3-(3-nitro-phenyl)-1-oxa-2,4-diaza-spiro[4.5]dec-2-en-4-ylamine(137557-26-7)

Safety Data

• Hazardous Substances Data: 137557-26-7(Hazardous Substances Data)

Upstream product

• 86467-47-2 4-methyl-cyclohexanone-hydrazone 
• 33512-94-6 m-nitrobenzhydroxamoyl chloride 

Downstream Products

• 137557-38-1 2-Chloro-N-[8-methyl-3-(3-nitro-phenyl)-1-oxa-2,4-diaza-spiro[4.5]dec-2-en-4-yl]-acetamide 
• 63002-57-3 2-(chloromethyl)-5-(3-nitrophenyl)-1,3,4-oxadiazole 

Relevant articles and documents

Ring Transformations of Heterocycles. Part 1. Transformation of 4-Amino-Δ2-1,2,4-oxadiazolines into 1,3,4-Oxadiazoles

3-Aryl-4-amino-Δ2-1,2,4-oxadiazolines 3 and their N-chloroacetyl derivatives 4, upon treatment with chloroacetic anhydride in refluxing toluene, afford 2-chloromethyl-5-aryl-1,3,4-oxadiazoles 5, suggesting the conversion sequence 3 -> 4 -> 5.The generality of the new ring transformation 4 -> 5 is supported similar conversion of other 4-(acylamino)-1,2,4-oxadiazolines 8 to 1,3,4-oxadiazoles 9.