13756-95-1Relevant academic research and scientific papers
Regio- und diastereoselektive Synthese von β-Aminoketonen durch Addition von Iminen an Iminiumsalze
Arend, Michael,Risch, Nikolaus
, p. 2861 - 2862 (2007/10/03)
Keywords: Aminoalkylierungen; Asymmetrische Synthesen; Imine; Mannich-Basen
γ-Methylenation of α,β-unsaturated ketones
Caputo,Ferreri,Mastroianni,Palumbo,Wenkert
, p. 2305 - 2312 (2007/10/02)
γ-Methylene derivatives of α,β-unsaturated ketones are obtained readily by a one-pot procedure exploiting the reaction of O-silylated dienolates with commercially available formaldehyde N,N-dimethyliminium chloride in anhydrous N,N-dimethylformamide, in s
A Convenient Regioselective Synthesis of Mannich Bases
Rochin, C.,Babot, O.,Dunogues, J.,Duboudin, F.
, p. 667 - 668 (2007/10/02)
A new, convenient regioselective process for aminomethylation of ketones is reported, involving the in situ formation of silyl enol ethers and iminium salts.
MANNICH REACTION UNDER HIGH PRESSURE. DIMETHYLAMINOMETHYLATION OF KETONES WITH BIS(DIMETHYLAMINO)METHANE UNDER MILD CONDITIONS
Matsumoto, Kiyoshi,Hashimoto, Shiro,Otani, Shinichi,Amita, Fujitsugu,Osugi, Jiro
, p. 585 - 590 (2007/10/02)
Dimethylaminomethylation of ketones with bis(dimethylamino)methane takes place cleanly in methanol at room temperature in the kiro bar region.
REGIOSELECTIVE MANNICH REACTIONS VIA TRIMETHYLSILYL ENOL ETHERS
Danishefski, S.,Prisbylla, M.,Lipisko, B.
, p. 805 - 808 (2007/10/02)
Site-specific reactions of trimethylsilyl enolates and trimethylsilyldienolates are described.
