13756-95-1

Basic information

• Product Name: Cyclohexanone, 2-[(dimethylamino)methyl]-2-methyl-
• CAS NO: 13756-95-1
• Molecular Formula: C10H19NO
• Molecular Weight: 169.267
• Mol File: 13756-95-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-[(dimethylamino)methyl]-2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-[(dimethylamino)methyl]-2-methyl-(13756-95-1)
• EPA Substance Registry System: Cyclohexanone, 2-[(dimethylamino)methyl]-2-methyl-(13756-95-1)

Safety Data

• Hazardous Substances Data: 13756-95-1(Hazardous Substances Data)

Upstream product

• 30354-18-8 N,N-dimethyl(methylene)ammonium chloride 
• 583-60-8 2-Methylcyclohexanone 
• 51-80-9 bis-(dimethylamino)methane 
• 19980-33-7 6-methyl-1-trimethylsiloxycyclohex-1-ene 
• 33797-51-2 eschenmoser's salt 
• 19980-35-9 1-trimethylsilyloxy-2-methyl-1-cyclohexene 
• 50-00-0 formaldehyd 
• 506-59-2 N,N-dimethylammonium chloride 

Relevant articles and documents

Regio- und diastereoselektive Synthese von β-Aminoketonen durch Addition von Iminen an Iminiumsalze

Keywords: Aminoalkylierungen; Asymmetrische Synthesen; Imine; Mannich-Basen

A Convenient Regioselective Synthesis of Mannich Bases

A new, convenient regioselective process for aminomethylation of ketones is reported, involving the in situ formation of silyl enol ethers and iminium salts.

REGIOSELECTIVE MANNICH REACTIONS VIA TRIMETHYLSILYL ENOL ETHERS

Site-specific reactions of trimethylsilyl enolates and trimethylsilyldienolates are described.