137567-92-1Relevant academic research and scientific papers
Microbial Oxidation of 7endo-Methylbicyclohept-2-en-6-one, 7,7-Dimethylbicyclohept-2-en-6-one and 2exo-Bromo-3endo-hydroxy-7,7-dimethylbicycloheptan-6-one using Acinetobacter NCIMB 9871
Carnell, Andrew J.,Roberts, Stanley M.,Sik, Vladimir,Willetts, Andrew J.
, p. 2385 - 2390 (1991)
A bio-Bayer-Villiger reaction using Acinetobacter NCIMB 9871 and the bicycloheptanone 2 provided the corresponding substituted oxabicyclooctanones 6 and 7.Similarly the ketones 3 and 9 furnished the lactones 8 and 10 respectively: the lactones 6, 7 and 10 were obtained in states of high optical purity.
The Meinwald reaction of alkyl propionates. Synthesis of the C1-C9 fragment of aurisides
Ríos, María-Yolanda,Velázquez, Francisco,Olivo, Horacio F.
, p. 6531 - 6537 (2007/10/03)
The C1-C9 northern fragment of aurisides 12a was prepared in eight steps and 41% overall yield starting from Grieco's bicyclic lactone (+)-4. The synthesis features a key stereoselective Meinwald reaction of the lithium enolate of alkyl propionate with the functionalized δ-lactone 3.
