Microbial Oxidation of 7endo-Methylbicyclohept-2-en-6-one, 7,7-Dimethylbicyclohept-2-en-6-one and 2exo-Bromo-3endo-hydroxy-7,7-dimethylbicycloheptan-6-one using Acinetobacter NCIMB 9871

DOI: 10.1039/P19910002385

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2385 - 2390 (1991)

Update date:2022-08-03

Topics:

Authors:

Carnell, Andrew J.

Roberts, Stanley M.

Sik, Vladimir

Willetts, Andrew J.

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Article abstract of DOI:10.1039/P19910002385

A bio-Bayer-Villiger reaction using Acinetobacter NCIMB 9871 and the bicycloheptanone 2 provided the corresponding substituted oxabicyclooctanones 6 and 7.Similarly the ketones 3 and 9 furnished the lactones 8 and 10 respectively: the lactones 6, 7 and 10 were obtained in states of high optical purity.

Full text of DOI:10.1039/P19910002385

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