137567-94-3

Upstream product

• 137503-35-6 (-)-(1'R,2'S)-2-(2'-hydroxymethylcyclopent-4'-enyl)propan-2-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 767-85-1 (+/-)-7,7-dimethylbicyclo<3.2.0>hept-2-en-6-one 
• 100898-02-0 (+)-(1R,5S)-7,7-dimethylbicyclo<3.2.0>hept-2-en-6-one 
• 137567-93-2 (+)-(1S,5R)-4,4-dimethyl-3-oxabicyclo<3.3.0>oct-6-en-2-one 

Relevant academic research and scientific papers

Microbial Oxidation of 7endo-Methylbicyclohept-2-en-6-one, 7,7-Dimethylbicyclohept-2-en-6-one and 2exo-Bromo-3endo-hydroxy-7,7-dimethylbicycloheptan-6-one using Acinetobacter NCIMB 9871

A bio-Bayer-Villiger reaction using Acinetobacter NCIMB 9871 and the bicycloheptanone 2 provided the corresponding substituted oxabicyclooctanones 6 and 7.Similarly the ketones 3 and 9 furnished the lactones 8 and 10 respectively: the lactones 6, 7 and 10 were obtained in states of high optical purity.