137601-89-9Relevant academic research and scientific papers
Direct synthesis of ethers from aldehydes and ketones. One-pot reductive etherification of benzaldehydes, alkyl aryl ketones, and benzophenones
Mochalov,Fedotov,Trofimova,Zefirov
, p. 503 - 512 (2016/06/13)
Benzyl alcohols formed by the reduction of benzaldehydes, alkyl aryl ketones, and benzophenones with sodium tetrahydridoborate in alcohols undergo in situ etherification with the solvent in the presence of a catalytic amount of HCl. Thus the process may be regarded as one-pot transformation of carbonyl compounds into the corresponding benzyl ethers. The yields of ethers depend on the substituent nature in the aromatic fragment of the initial carbonyl compound and on the alcohol used as reduction medium.
Hydrochloric acid as an efficient catalyst for intermolecular condensation of alcohols. A simple and highly efficient synthesis of unsymmetrical ethers from benzylic alcohols and alkanols
Mochalov,Fedotov,Trofimova,Zefirov
, p. 1217 - 1231 (2015/11/09)
Benzylic alcohols and diarylmethanols with electron-donating substituents in the aromatic ring reacted with aliphatic alcohols in the presence of a catalytic amount of HCl to give the corresponding alkyl arylmethyl ethers. The reactivity of diarylmethanols in the intermolecular dehydration depended on the nature of substituents in the aromatic rings and structure of aliphatic alcohol.
Substituent Effects in the Solvolysis of p-(2-Substituted Cyclopropyl)-α-Methylbenzyl Chlorides
Kusuyama, Yoshiaki,Kubo, Takako,Iyo, Masami,Kagosaku, Tamami,Tokami, Kenjiro
, p. 2954 - 2960 (2007/10/02)
The solvolysis rates of p-(cis- or trans-2-substituted cyclopropyl)-α-methylbenzyl chlorides including electron-donating and electron-attracting substituents relative to a hydrogen substituent were measured in 80percent aqueous acetone.The trans isomers w
