137618-68-9Relevant academic research and scientific papers
AN ASYMMETRIC SYNTHESIS OF GLYCEROL DERIVATIVES BY THE ENANTIOSELECTIVE ACYLATION OF PROCHIRAL GLYCEROL
Ichikawa, Junji,Asami, Masatoshi,Mukaiyama, Teruaki
, p. 949 - 952 (2007/10/02)
Optically active glycerol derivatives are obtained in up to 84percent e.e. by the selective acylation of the tin(II) alkoxides generated from 2-O-arylsulfonylglycerols and 1,1'-dimethylstannocene or (mehthylcyclopentadienyl)tin(II) chloride by the use of a chiral diamine derived from (S)-proline as a ligand.
